Accession Number : ADA231606
Title : Host Materials for 4d(N) and 5d(N) Transition-Metal Ions
Descriptive Note : Final rept.
Corporate Author : HARRY DIAMOND LABS ADELPHI MD
Personal Author(s) : Morrison, Clyde A
Report Date : Dec 1990
Pagination or Media Count : 49
Abstract : This report discusses ten compounds which are potential host materials for quadruply ionized elements with 4dn and 5dn electronic configurations. These compounds are ZrSiO4'HfGeO4'Li2ZrTeO6'Li2HfTeO6'Li6BeZrF12'ZrGeO4,ZrGeO8'ThSiO4' and ThGeO4 (in two forms: zircon and scheelite). The crystal-field components, Anm' are calculated for the Zr, Hf, and Th sites in each of the compounds. The site symmetry is S4 or D2d except for Li2XTeO6(X=Zr, Hf) which has C3 symmetry. Approximate parameters, F(k), Bnm(B, C, Dq), are given for the entire quadruply ionized 5dN configuration.
Descriptors : *IONIZATION , MATERIALS , CRYSTALS , SYMMETRY , PARAMETERS , SITES
Subject Categories : Inorganic Chemistry
Distribution Statement : APPROVED FOR PUBLIC RELEASE