Accession Number : ADA049555


Title :   High Energy Halogen Chemistry.


Descriptive Note : Final rept. 1 Dec 76-31 Dec 77,


Corporate Author : FLUOROCHEM INC AZUSA CALIF


Personal Author(s) : Baum,Kurt ; Berkowitz,Phillip T ; Lerdal,Duane A


Full Text : http://www.dtic.mil/get-tr-doc/pdf?AD=ADA049555


Report Date : Jan 1978


Pagination or Media Count : 48


Abstract : Contents: Nitrosilicone Chemistry; Chemistry of 2-Fluoro-2-nitropropanediol; Experimental -- Bis(2-fluoro-2,2-dinitropropyl)silanediols; Reaction of bis(2-fluoro-2, 2-dinitropropyl) silanediol with chlorotrimethylsilane, Bis(3-3-fluoro-3,3-dinitropropyl)polysiloxane, Reaction of Bis(N-pyrrolidino-N'-Phenylureido)dimethylsilane with Bis-2-fluoro-2,2-dinitropropyl)silanediol, 2-Fluoro-2-nitro-1,3-propanediol, 2-Fluoro-3-hydroxy-2-nitro-1-propyl p-Toluenesulfonate, 2-Fluoro-2-nitro-1,3-propylene Di-p-toluenesulfonate, 2,6-Difluoro-7-hydroxy-2,6-dinitro-4-oxa-1-heptyl p-Toluenesulfonate, 3-Azide-2-fluoro-2-nitro-1-propanol, 3-Bromo-2-fluoro-2-nitro-1-propanol, 1,3-Diazido-2-fluoro-2-nitropropane, 2-Fluoro-3-hydroxy-2-nitro-1-propyl Triflate, 2-Fluoro-2-nitro-1,3-propylene Ditriflate, 3-Fluoro-3-nitrooxetane, Reaction of 2-Fluoro-3-hydroxy-2-nitro-1-propyl Triflate with Pyridine, 3-Chloro-2-fluoro-2-nitro-1-propanol, Reaction of 2,2-Dinitro-1,3-propanediol with Triflic Anhydride; References; Appendices -- Synthesis of Organosilanes and Polysiloxanes with Nitro and Fluoro Substituents, Synthesis of Bis(3,3-dinitrobutyl)cyclopolysiloxanes; and Distribution List.


Descriptors :   *POLYMERS , *POLYMERIZATION , *SYNTHESIS(CHEMISTRY) , *SILICONES , *FLUORINE COMPOUNDS , *NITRATES , NUCLEAR MAGNETIC RESONANCE , MOLECULAR WEIGHT , EXPLOSIVES , SILOXANES , HIGH ENERGY , PROPELLANTS , CHEMICAL REACTIONS , SILANES , PHENYL RADICALS , INFRARED SPECTRA , FLUORINATION , PROPANE , ALKYL RADICALS , ALCOHOLS , CHLORINE COMPOUNDS , DIFFERENTIAL THERMAL ANALYSIS , BROMINE COMPOUNDS , OXETANES


Subject Categories : Polymer Chemistry
      Ammunition and Explosives


Distribution Statement : APPROVED FOR PUBLIC RELEASE